{"id":18818,"date":"2024-06-17T19:20:09","date_gmt":"2024-06-18T03:20:09","guid":{"rendered":"https:\/\/integratechem.com\/yuksek-saflikta-tributil-sitrat-akiskanlastirici\/"},"modified":"2026-04-02T06:51:44","modified_gmt":"2026-04-02T14:51:44","slug":"high-purity-tributyl-citrate-plasticizer","status":"publish","type":"post","link":"https:\/\/integratechem.com\/tr\/high-purity-tributyl-citrate-plasticizer\/","title":{"rendered":"Y\u00fcksek Safl\u0131kta Tributil Sitrat Ak\u0131\u015fkanla\u015ft\u0131r\u0131c\u0131"},"content":{"rendered":"\n

1. Y\u00fcksek Safl\u0131kta Tributil Sitrat Ak\u0131\u015fkanla\u015ft\u0131r\u0131c\u0131 Nedir<\/h2><\/div>\n\n

Y\u00fcksek safl\u0131kta tributil sitrat plastikle\u015ftirici, \u00e7o\u011fu organik \u00e7\u00f6z\u00fcc\u00fcde \u00e7\u00f6z\u00fcnebilen renksiz ya\u011fl\u0131 bir s\u0131v\u0131 olan n-b\u00fctanol\u00fcn sitrik asit esteridir. \u00c7in tedarik\u00e7ilerinin sa\u011flad\u0131\u011f\u0131 toksik olmayan bir plastikle\u015ftiricidir. \u00c7in’deki \u00fcreticiler ve fabrikalar bunu toksik olmayan PVC’yi gran\u00fcle etmek ve g\u0131da ambalaj malzemeleri \u00fcretmek i\u00e7in kullanmaktad\u0131r. <\/p>\n\n

\"Y\u00fcksek<\/figure><\/div>\n\n

2. Hangi \u00f6zelliklere sahiptir<\/h2><\/div>\n\n

Ya\u011fl\u0131 alkol\u00fcn bir karboksilik asit esteri olarak, \u00fcreticiler ve tedarik\u00e7iler bunun bir karboksilik asit t\u00fcrevine ait oldu\u011funu ve bir karbonil grubu i\u00e7erdi\u011fini d\u00fc\u015f\u00fcn\u00fcrler. Bu nedenle, y\u00fcksek safl\u0131kta tributil sitrat plastikle\u015ftirici, kar\u015f\u0131l\u0131k gelen asit ve alkolden daha d\u00fc\u015f\u00fck kaynama noktas\u0131na sahip polar bir bile\u015fiktir. Ve ayn\u0131 say\u0131da karbon atomuna sahip aldehitlere veya ketonlara benzer. U\u00e7ucudur ve kokusu vard\u0131r. <\/p>\n\n

Fabrikalar ve \u00fcreticiler sitrik asit esterinin su ile reaksiyona girerek sitrik asit ve n-b\u00fctanol \u00fcretmesini sa\u011flayabilir. Hidroliz kabiliyeti, a\u00e7il halojen\u00fcrler ve anhidritlerinkinden daha az, ancak amidlerinkinden daha fazlad\u0131r. \u00c7in’deki tedarik\u00e7iler ve \u00fcreticiler bu reaksiyonlar\u0131 HOH molek\u00fcl\u00fcndeki H’nin a\u00e7il gruplar\u0131 ile yer de\u011fi\u015ftirmesi olarak g\u00f6rmektedir. Asil halojen\u00fcrler ve anhidritler en g\u00fc\u00e7l\u00fc asilasyon kabiliyetine sahiptir, bu nedenle fabrikalar ve \u00fcreticiler genellikle organik sentezde asilleyici ajanlar olarak kullan\u0131rlar. <\/p>\n\n

\u00c7in’deki tedarik\u00e7iler esterlerin alkali \u00e7\u00f6zeltide hidrolizini sabunla\u015fma olarak adland\u0131rmaktad\u0131r, \u00e7\u00fcnk\u00fc s\u0131v\u0131 ve kat\u0131 ya\u011flar\u0131n alkali hidrolizi ile elde edilen y\u00fcksek ya\u011f asidi tuzlar\u0131 sabundur.<\/p>\n\n

Esterler hidroklorik asit veya sodyum alkol kataliz\u00f6rl\u00fc\u011f\u00fcnde alkollerle reaksiyona girdi\u011finde, ba\u015fka bir alkol ve ester \u00fcretmi\u015f oluruz. Bu reaksiyona transesterifikasyon diyoruz. Ayn\u0131 zamanda tersinirdir. \u00d6rne\u011fin, trietil sitrat n-b\u00fctanol ile reaksiyona girerek tributil sitrat ve etanol olu\u015fturur. <\/p>\n\n

Ya\u011f asidi esterleri amonyak ile reaksiyona girerek amidler olu\u015fturabilir. \u00d6rne\u011fin, Tributil Sitrat (TBC)<\/a>, Asetil Tributil Sitrat (ATBC)<\/a> olu\u015fturmak i\u00e7in asetillenir. <\/p>\n\n

Y\u00fcksek safl\u0131kta tributil sitrat, tersiyer alkoller \u00fcretmek i\u00e7in Grignard reaktifleri ile reaksiyona girebilir.<\/p>\n\n

Asetil trib\u00fctil sitrat\u0131n<\/a> indirgenmesi karboksilik asitlerden daha kolayd\u0131r. Sentezde, karboksilik asitler genellikle esterler yoluyla alkollere indirgenir. En yayg\u0131n kullan\u0131lan indirgeyici madde sodyum art\u0131 etanold\u00fcr. Elde edilen alkoller ya orijinal esterle\u015ftirmede kullan\u0131lan alkol ya da a\u00e7il grubunun indirgenmesiyle olu\u015fan birincil alkold\u00fcr. <\/p>\n\n

3. Reaksiyon mekanizmas\u0131 nedir<\/h2><\/div>\n\n

\u0130nsanlar sitrik asit ve n-b\u00fctanol\u00fc az miktarda asidik kataliz\u00f6r varl\u0131\u011f\u0131nda \u0131s\u0131tarak y\u00fcksek safl\u0131kta tributil sitrat plastikle\u015ftirici \u00fcretirler. Kataliz\u00f6r kuru hidrojen klor\u00fcr ve g\u00fc\u00e7l\u00fc bir asit iyon de\u011fi\u015ftirici re\u00e7inedir. Ayr\u0131ca fabrikalar konsantre s\u00fclf\u00fcrik asit kullan\u0131r. Bu reaksiyonu esterle\u015fme olarak adland\u0131r\u0131yoruz. Esterifikasyon trib\u00fctil sitrat olu\u015fturdu\u011funda, sitrik asit ve n-b\u00fctanol molek\u00fcllerinin dehidrasyonu i\u00e7in iki olas\u0131 yol vard\u0131r. \u00c7al\u0131\u015fmalar, kimyasal ba\u011f\u0131n kopmas\u0131n\u0131n a\u00e7il grubu ile oksijen aras\u0131nda ger\u00e7ekle\u015fti\u011fini g\u00f6stermi\u015ftir. Yani, reaksiyon s\u0131ras\u0131nda olu\u015fan su, sitrik asitteki hidroksil grubundan ve n-b\u00fctanol i\u00e7indeki hidrojen ba\u011f\u0131ndan gelir. <\/p>\n\n

Esterle\u015fme tersinir bir reaksiyondur. Denge tamamland\u0131\u011f\u0131nda, belirli say\u0131da reaktan ve \u00fcr\u00fcn vard\u0131r. \u00d6rne\u011fin, ayn\u0131 1 mol sitrik asit ve 3 mol n-butanol az miktarda s\u00fclf\u00fcrik asit varl\u0131\u011f\u0131nda reaksiyona girdi\u011finde, denge olu\u015ftu\u011funda, sitrik asit ve n-butanol\u00fcn bir k\u0131sm\u0131 y\u00fcksek safl\u0131kta trib\u00fctil sitrat plastikle\u015ftirici haline gelir. Is\u0131tma ve kataliz\u00f6r ekleme sadece reaksiyon h\u0131z\u0131n\u0131 h\u0131zland\u0131rabilir, ancak denge malzemesinin bile\u015fimi \u00fczerinde hi\u00e7bir etkisi yoktur. <\/p>\n\n

4. Y\u00fcksek Safl\u0131kta Tributil Sitrat Plastifiyan \u00fcretimi ve verimi nas\u0131l iyile\u015ftirilir<\/h2><\/div>\n\n

Verimi art\u0131rmak i\u00e7in fabrikalar genellikle fazla sitrik asit veya n-b\u00fctanol ekler. Ya da insanlar \u00fcretilen suyu reaksiyon kar\u0131\u015f\u0131m\u0131ndan \u00e7\u0131kar\u0131r. \u00dcretilen esterin kaynama noktas\u0131 \u00e7ok d\u00fc\u015f\u00fckse, \u00c7in’deki \u00fcreticiler ve tedarik\u00e7iler esterin buharla\u015fmas\u0131n\u0131 sa\u011flayabilir. Ancak tributil sitrat\u0131n kaynama noktas\u0131 150\u00b0C’dir, bu nedenle \u00f6nce suyu buharla\u015ft\u0131rd\u0131k. K\u0131sacas\u0131, insanlar verimi art\u0131rmak i\u00e7in dengeyi bozdular. End\u00fcstriyel \u00fcretimde, y\u00fcksek safl\u0131kta trib\u00fctil sitrat plastikle\u015ftirici ve suyun s\u00fcrekli kaynayan kar\u0131\u015f\u0131m\u0131n\u0131 buharla\u015ft\u0131rmak i\u00e7in fazla sitrik asit kullan\u0131yoruz. Ve sonra insanlar s\u00fcrekli \u00fcretim i\u00e7in tributil sitrat ve suyu buharla\u015ft\u0131rmak i\u00e7in s\u00fcrekli olarak sitrik asit ve b\u00fctanol eklediler. <\/p>\n\n

5. Y\u00fcksek Safl\u0131kta Tributil Sitrat Ak\u0131\u015fkanla\u015ft\u0131r\u0131c\u0131 Uygulamas\u0131<\/h2><\/div>\n\n

Sitrat esterleri amonyak ile reaksiyona girerek amid olu\u015fturabilir. Trib\u00fctil sitrat, CAS No 77 90 7 asetil trib\u00fctil sitrat olu\u015fturmak \u00fczere asetillenir. <\/p>\n\n

Tributil Sitrat (TBC), \u00e7o\u011fu organik \u00e7\u00f6z\u00fcc\u00fcde \u00e7\u00f6z\u00fcnebilen renksiz ya\u011fl\u0131 bir s\u0131v\u0131d\u0131r. D\u00fc\u015f\u00fck u\u00e7uculu\u011fa, y\u00fcksek plastikle\u015ftirme verimlili\u011fine sahiptir ve re\u00e7inede kolayca \u00e7\u00f6z\u00fcn\u00fcr. \u00dcr\u00fcn\u00fcn d\u00fc\u015f\u00fck s\u0131cakl\u0131k direncini, su direncini ve k\u00fcf direncini art\u0131rabilir. Tributil Sitrat, fabrikalar\u0131n toksik olmayan PVC gran\u00fclasyonunda plastikle\u015ftirici olarak kulland\u0131\u011f\u0131 toksik olmayan bir plastikle\u015ftiricidir. Ayr\u0131ca uygulamalar g\u0131da ambalaj\u0131, \u00e7ocuk oyuncaklar\u0131, t\u0131bbi malzemeler, polivinil klor\u00fcr ve vinil klor\u00fcr kopolimer \u00fcretimindedir. <\/p>\n\n

6. Y\u00fcksek Safl\u0131kta Tributil Sitrat Ak\u0131\u015fkanla\u015ft\u0131r\u0131c\u0131n\u0131n Hidroliz Reaksiyonu<\/h2><\/div>\n\n

T\u00fcm esterler asidik veya alkali \u00e7\u00f6zeltilerde n\u00f6tr \u00e7\u00f6zeltilere g\u00f6re daha kolay hidrolize olur. Asidik \u00e7\u00f6zeltiler hidrojen iyonlar\u0131 sa\u011flad\u0131\u011f\u0131ndan, oksijeni pozitif y\u00fckl\u00fc hale getirmek i\u00e7in polar karbonil oksijen ile birle\u015febilirler. B\u00f6ylece \u03c0 elektron bulutu oksijene daha fazla aktar\u0131l\u0131r. Bu da karbonil karbonunu pozitif y\u00fckl\u00fc ve n\u00fckleofilik kat\u0131lma reaksiyonlar\u0131na daha yatk\u0131n hale getirir. Su gibi daha zay\u0131f n\u00fckleofiller bile n\u00fckleofilik kat\u0131lma reaksiyonlar\u0131na girebilir. Asidin katalitik etkisi olmadan, esterlerin hidroliz h\u0131z\u0131 \u00e7ok yava\u015ft\u0131r. \u00dcreticiler ve fabrikalar esterlerin hidroliz reaksiyonu i\u00e7in \u0131s\u0131tmal\u0131 ve bir kataliz\u00f6r eklemelidir. <\/p>\n\n

Esterlerin hidroliz reaksiyonu tersinir bir reaksiyondur ve insanlar b\u00fcy\u00fck miktarda su varl\u0131\u011f\u0131nda reaksiyonun tamamlanmas\u0131n\u0131 sa\u011flayabilir. E\u015fitolar esterler ve su, asidik veya n\u00f6tr \u00e7\u00f6zeltilerde dengeli bir kar\u0131\u015f\u0131m olu\u015ftururken, alkali \u00e7\u00f6zeltilerde, hidroksit iyonlar\u0131 g\u00fc\u00e7l\u00fc n\u00fckleofiller oldu\u011fundan, karboksilik asitler bir kez \u00fcretildi\u011finde, hemen alkalilerle tuzlar olu\u015fturarak dengeyi bozar ve hidroliz reaksiyonunun sonuna kadar ilerlemesine izin verir. <\/p>\n\n

7. Y\u00fcksek Safl\u0131kta Tributil Sitrat Plastifiyan \u00fcr\u00fcn kalitesi nas\u0131l sa\u011flan\u0131r<\/h2><\/div>\n\n

Fabrikam\u0131z geli\u015fmi\u015f \u00fcretim ekipmanlar\u0131na, olgun \u00fcretim teknolojisine, eksiksiz test cihazlar\u0131na ve standartla\u015ft\u0131r\u0131lm\u0131\u015f analiz y\u00f6ntemlerine sahiptir ve s\u00fcrekli esterle\u015ftirme, dam\u0131tma ay\u0131rma, n\u00f6trle\u015ftirme ve su y\u0131kama \u00fcretim s\u00fcrecini benimser, b\u00f6ylece \u00fcr\u00fcndeki serbest asit ve su i\u00e7eri\u011fi d\u00fc\u015f\u00fckt\u00fcr. Bu nedenle, \u00fcr\u00fcn y\u00fcksek i\u00e7eri\u011fe, d\u00fc\u015f\u00fck asit de\u011ferine ve su i\u00e7eri\u011fine sahiptir, hidrolize edilmesi kolay de\u011fildir ve istikrarl\u0131 bir kaliteye sahiptir. Bu, yerli ve yabanc\u0131 m\u00fc\u015fteriler taraf\u0131ndan derinden tan\u0131nmaktad\u0131r. <\/p>\n\n

Hot Tags: tedarik\u00e7iler \u00c7in, \u00fcreticiler, fabrika, CAS No 77-94-1<\/a>, Toksik Olmayan Plastifiyan<\/a>, Sel\u00fcloz re\u00e7ineleri i\u00e7in Plastifiyan<\/a>, PVC Plastifiyan<\/a>, Tributil Ester<\/a><\/p>\n\n

\u0130lgili Ba\u011flant\u0131lar: CAS No 77 89 4<\/a>, CAS No 77 90 7<\/a>, CAS No 77 93 0<\/a>, CAS No 77 94 1<\/a>, Tributil Sitrat (TBC)<\/a>, Y\u00fcksek Kaliteli Plastikle\u015ftirici TBC Tributil Sitrat<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

1. 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