{"id":19698,"date":"2024-06-09T18:58:35","date_gmt":"2024-06-10T02:58:35","guid":{"rendered":"https:\/\/integratechem.com\/n-cas-77-90-7\/"},"modified":"2024-11-14T23:24:19","modified_gmt":"2024-11-15T07:24:19","slug":"cas-no-77-90-7","status":"publish","type":"post","link":"https:\/\/integratechem.com\/it\/cas-no-77-90-7\/","title":{"rendered":"N. CAS 77 90 7"},"content":{"rendered":"\n

Quali reazioni possono subire gli esteri?<\/h2>\n\n

Gli esteri possono reagire con l’ammoniaca per formare ammidi. Ad esempio, il citrato di tributile<\/a> viene acetilato per formare il citrato di tributile<\/a>(CAS n. 77 90 7). <\/p>\n\n

L’acetil tributil citrato pu\u00f2 reagire con l’acqua per formare gli acidi carbossilici e gli alcoli corrispondenti. Ad esempio, il tributilcitrato viene idrolizzato per formare acido citrico e n-butanolo. <\/p>\n\n

La capacit\u00e0 di idrolisi del n. CAS 77 90 7<\/strong><\/h2>\n\n

La capacit\u00e0 di idrolisi degli esteri \u00e8 inferiore a quella degli alogenuri acilici e delle anidridi, ma superiore a quella delle ammidi. Queste reazioni vengono considerate come la sostituzione di H nella molecola HOH con gruppi acilici. Gli alogenuri acilici e le anidridi hanno la capacit\u00e0 acilante pi\u00f9 forte, quindi spesso vengono utilizzati come agenti acilanti nella sintesi organica. <\/p>\n\n

<\/p>\n\n

\"Cina<\/figure><\/div>\n\n

Perch\u00e9 gli esteri hanno una forte capacit\u00e0 di idrolisi in soluzioni alcaline e acide<\/h2>\n\n

Il citrato di acetile tributile (CAS n. 77 90 7) viene idrolizzato pi\u00f9 facilmente in soluzioni acide o alcaline che in soluzioni neutre. Poich\u00e9 le soluzioni acide forniscono ioni idrogeno, questi possono legarsi all’ossigeno carbonilico polare, rendendo l’ossigeno carico positivamente, quindi la nuvola di elettroni \u03c0 viene trasferita maggiormente all’ossigeno, rendendo il carbonile carico positivamente e pi\u00f9 incline alle reazioni di addizione nucleofila. Anche i nucleofili pi\u00f9 deboli, come l’acqua, possono subire reazioni di addizione nucleofila. <\/p>\n\n

Le caratteristiche di idrolisi del n. CAS 77 90 7<\/strong> in soluzioni alcaline<\/h2>\n\n

In condizioni alcaline, l’idrolisi degli esteri reagisce generalmente con l’idrossido di sodio, che richiede anche il riscaldamento. Questa reazione \u00e8 irreversibile e completa. L’idrolisi degli esteri in soluzioni alcaline viene chiamata saponificazione, perch\u00e9 i sali di acidi grassi superiori ottenuti dall’idrolisi alcalina di oli e grassi sono saponi. <\/p>\n\n

Le caratteristiche di idrolisi degli esteri in soluzioni acide<\/h2>\n\n

Prendiamo come esempio il numero CAS 77 90 7 acetil trietil citrato. L’alcol generato dopo la reazione \u00e8 ancora etanolo, ma grazie alla presenza di idrossido di sodio, alla fine si ottiene citrato di sodio. Queste due condizioni sono i modi principali in cui avviene l’idrolisi degli esteri. L’idrolisi in condizioni acide \u00e8 incompleta e reversibile, mentre quella in condizioni alcaline \u00e8 completa e irreversibile. <\/p>\n\n

Link correlati: N. CAS 77 89 4<\/a>, Plastificante a base di citrato di tributile di elevata purezza<\/a>, N. CAS 77 94 1<\/a>, Citrato di tributile (TBC)<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

Quali reazioni possono subire gli esteri? Gli esteri possono reagire con l’ammoniaca per formare ammidi. 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Gli esteri possono reagire con l’ammoniaca per formare ammidi. Ad esempio, il citrato di […]","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"https:\/\/integratechem.com\/it\/wp-json\/wp\/v2\/posts\/19698","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/integratechem.com\/it\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/integratechem.com\/it\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/integratechem.com\/it\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/integratechem.com\/it\/wp-json\/wp\/v2\/comments?post=19698"}],"version-history":[{"count":1,"href":"https:\/\/integratechem.com\/it\/wp-json\/wp\/v2\/posts\/19698\/revisions"}],"predecessor-version":[{"id":19699,"href":"https:\/\/integratechem.com\/it\/wp-json\/wp\/v2\/posts\/19698\/revisions\/19699"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/integratechem.com\/it\/wp-json\/wp\/v2\/media\/17079"}],"wp:attachment":[{"href":"https:\/\/integratechem.com\/it\/wp-json\/wp\/v2\/media?parent=19698"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/integratechem.com\/it\/wp-json\/wp\/v2\/categories?post=19698"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/integratechem.com\/it\/wp-json\/wp\/v2\/tags?post=19698"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}