{"id":19952,"date":"2024-06-09T18:58:35","date_gmt":"2024-06-10T02:58:35","guid":{"rendered":"https:\/\/integratechem.com\/cas-nr-77-90-7\/"},"modified":"2024-11-19T04:51:57","modified_gmt":"2024-11-19T12:51:57","slug":"cas-no-77-90-7","status":"publish","type":"post","link":"https:\/\/integratechem.com\/de\/cas-no-77-90-7\/","title":{"rendered":"CAS-Nr. 77 90 7"},"content":{"rendered":"\n

Welche Reaktionen k\u00f6nnen Ester eingehen?<\/h2>\n\n

Ester k\u00f6nnen mit Ammoniak reagieren und Amide bilden. Zum Beispiel macht man Tributylcitrat<\/a> acetyliert, um CAS Nr. 77 90 7 Acetyltributylcitrat<\/a> zu bilden. <\/p>\n\n

Acetyltributylcitrat kann mit Wasser reagieren und die entsprechenden Carbons\u00e4uren und Alkohole bilden. Tributylcitrat wird zum Beispiel zu Zitronens\u00e4ure und n-Butanol hydrolysiert. <\/p>\n\n

Die Hydrolysef\u00e4higkeit von CAS-Nr. 77 90 7<\/strong><\/h2>\n\n

Die Hydrolysef\u00e4higkeit von Estern ist geringer als die von Acylhalogeniden und Anhydriden, aber gr\u00f6\u00dfer als die von Amiden. Man betrachtet diese Reaktionen als den Ersatz von H im HOH-Molek\u00fcl durch Acylgruppen. Acylhalogenide und Anhydride haben die st\u00e4rkste acylierende F\u00e4higkeit, daher verwenden wir sie oft als Acylierungsmittel in der organischen Synthese. <\/p>\n\n

<\/p>\n\n

\"China<\/figure><\/div>\n\n

Warum Ester eine starke Hydrolysef\u00e4higkeit in alkalischen und sauren L\u00f6sungen haben<\/h2>\n\n

CAS-Nr. 77 90 7 Acetyltributylcitrat wird in sauren oder alkalischen L\u00f6sungen leichter hydrolysiert als in neutralen L\u00f6sungen. Da saure L\u00f6sungen Wasserstoffionen bereitstellen, k\u00f6nnen diese an den polaren Carbonylsauerstoff binden, wodurch der Sauerstoff positiv geladen wird, so dass die \u03c0-Elektronenwolke st\u00e4rker auf den Sauerstoff \u00fcbertragen wird, wodurch der Carbonylkohlenstoff positiv geladen und anf\u00e4lliger f\u00fcr nukleophile Additionsreaktionen wird. Auch schw\u00e4chere Nukleophile, wie z.B. Wasser, k\u00f6nnen nukleophile Additionsreaktionen eingehen. <\/p>\n\n

Die Hydrolyseeigenschaften von CAS-Nr. 77 90 7<\/strong> in alkalischen L\u00f6sungen<\/h2>\n\n

Unter alkalischen Bedingungen reagiert die Esterhydrolyse im Allgemeinen mit Natriumhydroxid, das ebenfalls erhitzt werden muss. Diese Reaktion ist irreversibel und vollst\u00e4ndig. Die Hydrolyse von Estern in alkalischen L\u00f6sungen wird als Verseifung bezeichnet, weil die h\u00f6heren Fetts\u00e4uresalze, die bei der alkalischen Hydrolyse von \u00d6len und Fetten entstehen, Seifen sind. <\/p>\n\n

Die Hydrolyseeigenschaften von Estern in sauren L\u00f6sungen<\/h2>\n\n

Nehmen Sie die CAS-Nr. 77 90 7 Acetyltriethylcitrat als Beispiel. Der nach der Reaktion entstandene Alkohol ist immer noch Ethanol, aber durch die Anwesenheit von Natriumhydroxid haben wir schlie\u00dflich Natriumcitrat erhalten. Diese beiden Bedingungen sind die Hauptwege, auf denen die Esterhydrolyse stattfindet. Die Hydrolyse unter sauren Bedingungen ist unvollst\u00e4ndig und reversibel, w\u00e4hrend die Hydrolyse unter alkalischen Bedingungen vollst\u00e4ndig und irreversibel ist. <\/p>\n\n

Verwandte Links: CAS-Nr. 77 89 4<\/a>, Hochreiner Tributylcitrat-Weichmacher<\/a>, CAS-Nr. 77 94 1<\/a>, Tributylcitrat (TBC)<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

Welche Reaktionen k\u00f6nnen Ester eingehen? Ester k\u00f6nnen mit Ammoniak reagieren und Amide bilden. Zum Beispiel macht man Tributylcitrat acetyliert, um […]<\/p>\n","protected":false},"author":2,"featured_media":17076,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"nf_dc_page":"","_uag_custom_page_level_css":"","_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"_jetpack_memberships_contains_paid_content":false,"footnotes":""},"categories":[695],"tags":[705,704,727,733],"class_list":["post-19952","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-showroom-de","tag-acetyl-tributyl-citrate-de","tag-atbc-de","tag-pvc-plasticizer-de","tag-tributyl-ester-de"],"yoast_head":"\nChina CAS Nr. 77 90 7 Hersteller Fabrik Lieferanten<\/title>\n<meta name=\"description\" content=\"Integratechem bietet Citratester zum g\u00fcnstigsten Preis an. 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Ester k\u00f6nnen mit Ammoniak reagieren und Amide bilden. Zum Beispiel macht man Tributylcitrat acetyliert, um […]","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"https:\/\/integratechem.com\/de\/wp-json\/wp\/v2\/posts\/19952","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/integratechem.com\/de\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/integratechem.com\/de\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/integratechem.com\/de\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/integratechem.com\/de\/wp-json\/wp\/v2\/comments?post=19952"}],"version-history":[{"count":1,"href":"https:\/\/integratechem.com\/de\/wp-json\/wp\/v2\/posts\/19952\/revisions"}],"predecessor-version":[{"id":19953,"href":"https:\/\/integratechem.com\/de\/wp-json\/wp\/v2\/posts\/19952\/revisions\/19953"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/integratechem.com\/de\/wp-json\/wp\/v2\/media\/17076"}],"wp:attachment":[{"href":"https:\/\/integratechem.com\/de\/wp-json\/wp\/v2\/media?parent=19952"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/integratechem.com\/de\/wp-json\/wp\/v2\/categories?post=19952"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/integratechem.com\/de\/wp-json\/wp\/v2\/tags?post=19952"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}